So, we can take a measure of the temperature of the universe and we have really good evidence that the universe is isotropic and homogeneous. We'll see that we learn a lot more from the cosmic background in the 2000s than just that it exists but that's not evidence, what I've given you so far is far from convincing evidence for the Big Bang. Some of the best evidence for the Big Bang is a story that is rarely told and is, because it's a bit technical, but I want to tell it and I want I think we can appreciate what's going on. So, you know this is the story of Big Bang nucleosynthesis and it's interesting we talked about stars and nucleosynthesis and the R process and the S process and supernovae as creating all the heavy elements. But we never discussed the production of Helium, of course, Helium is produced in stars. But we saw that not in a quantity that would significantly alter the sort of cosmic abundance of Helium. Where did the 25% of the universe that is Helium come from? And this becomes clear in a project undertaken by George Gamow and his student, Alpher, in 1948 and they actually, Gamow's agenda, the time stellar dynamics was not nearly as well understood as it is today, Gamow's agenda was to show that back in the hot, dense, early universe all of the elements were, in fact synthesized and that the current cosmic abundances could be explained by the Big Bang. So, what's the idea? If you go far enough in the past, there was a brief episode in the early history of the universe where temperatures were high and densities as high as in the interior of stars. So, there was fusion going on everywhere at every position, right here, what is the position that is right here, right now, a long time ago was a part of a very hot, dense plasma where fusion was going on. So, fusion was going on pervasively, and Gamow's idea was that this is where heavier elements than hydrogen were created. It turns out that, remember that the crucial step for synthesizing heavy elements was the triple alpha process. the triple alpha process worked in the context of a star that had long enough time to maintain a stellar core as high density for a while. only very rapid processes work in the context of Big Bang nucleosynthesis because very rapidly, the world cools and dilutes, and densities decrease, you don't have the stellar envelope holding things in, but it does correctly predict the Helium abundance, let's see how that works. So, here's the assumptions. We're going to assume, that reactions maintain thermal status of thermal equilibrium in the gas, this hot dense plasma, in the context of an expanding flat universe. This means that the reactions proceed rapidly enough that before the universe has diluted things away chemical abundances can adjust. And, of course, at some point, it stops and that is the, at that point, you sort of freeze in the situation that you have. So, let's see how that works. remember that at high temperature, we have relativistic particles and the number density of a relativistic particle is simply given by the Stefan-Boltzmann Law. The energy density of a relativistic gas is proportional to t^4, the energy, average energy of the particles proportional to t, so the number density of relativistic particles is proportional to kT^3, and in particular, is essentially independent of their masses. On the other hand, at the low energy, at low temperature we have non-relativistic particles. And if you imagine that there are processes that can create all kinds of particles then you can think of particles as energy states, as and just in the way that in a gas with temperature T, there can be a tail, remember, of particles, Helium particles, whose speeds are 10 times the average thermal speed but that's an exponential decaying tail. the similar process holds in creating particles of the, thermal equilibrium where there are processes that can create and destroy particles at temperatures below where kBT is less than mc^2 the number density of a particle decreases exponentially with the ratio of rest energy to the thermal energy, particles that are way massive than the pervase, more massive than the pervasive temperature are unlikely to be found and as this exponent approaches 0, you'll exactly go over to the relativistic mass indpendent density. So, whose radiation? Well, that depends on your temperature. I remind you of our list of particles. I've slightly increased it from back when you were talking about the sun, you see their charges. And based on their masses, I can tell you that protons, for example, become relativistic of temperatures of about 10^13 K. And this g is that geometric factor, the number of degenerate states that a particle has that relates how many of these there are to how many photons there are. So, that's an extra factor of our [UNKNOWN] density. protons become relativistic at 10^13 Kelvin. What about neutrons? Well, neutrons are a little bit more massive than protons so they become relativistic at a temperature that is just a little bit higher 10^13, but the main important difference is that the temperature difference for neutrons to become relativistic is about 1.5*10^10 K. Electrons, being much lighter become relativistic at about 6 billion Kelvin. neutrinos, as far as we know, are massless. They can become relativistic at any temperature. Certainly a photon, which is exactly massless is relativistic at all, temperatures isn't always moves at the speed of light. muons, intermediate mass become relativistic at about a trillion K. And another kind of particle called the pion, this is not the right number and the mass of a pion is 140 some, 2 maybe MeV and so they become relativistic at about 1.6 trillion degrees, there's 3 different kinds of them with three different charges and this is a relic from an old table. okay, so there's a collection of particles and as temperatures increase moving into the past, more and more of them are relativistic. So, what has this got to tell us? conversely as temperatures cool, less and less of them are relativistic. So, let's start at the beginning with a very hot universe with a temperature above a trillion Kelvin. neutrons and protons are marginally non-relativistic but of all the species that are relativistic, then you have thermal equilibrium. And in thermal equilibrium, as we'll see, the processes of Physics do not distinguish particles from antiparticles so there is as many antielectrons as there are electrons. There is as many antiprotons as protons, there are almost as many. So, there are large quantites of antiprotons and protons, antineutrinos and neutrinos, antimuons and muons, and so on. the ratio between the number density of neutrons and protons is given by the ratio of those two exponentials which is proportional to the difference of their masses in units of kT and since the difference in their masses is small compared to the temperature even though they're not relativistic, there's about the same number of neutrons as protons. Now, as the universe cools by about a factor of 10, by the way, these temperatures obtained for the first ten thousandths of a second after the Planck time, so we're deep into the radiation dominated era and all of the exciting events occur very early in the history of the univesre. by that time temperatures have decreased by about 10^11 Kelvin. muons stop being relativistic. When muons slow down, these muons and antimuons find each other, they annihilate. most of the muons are gone, only a small remnant of actual muons survive. The excess muons over antimuons, we'll talk about that later, and the muons are gone by this time. If you plug into this expression there's still equilibrium, the number of neutrons, ratio of neutron number to proton number is about 0.86 and note [COUGH] that neutrons, unlike protons, are unstable. Of course, they decay. But they decay in 15 minutes. Neutron decay is not playing a significant role yet. It will later. as the temperature cools further by the time we get to 30 billion K at time about a tenth of a second after the Big Bang neutrinos, because of the slow rates of the weak interactions essentially decouple at this point neutrons or neutron to proton ratio has decreased to about 0.6. And by the time you get to 5 billion Kelvin at a few tens of seconds electrons have become, are beginning to become non-relativistic, electrons and positrons annihilate, producing a lot of photons. Notice that the, the neutrinos are, are already decoupled. So, at the time that the neutrinos decoupled, of course, neutrinos and photons were all strongly interacting. There were two gases that could exchange energy, they had the same temperature. So, do we expect a gas of primordial neutrinos, just as there are cosmic microwave backgrounds, sort of, except that when all these electrons annihilated electron and positron produce two photons with energy 511 KeV each. And so this produces more photons heating the photon gas injecting energy into the photon gas that is then rethermalized. And for that reason, the photons at that point are harder than neutrinos. From that moment on after recombination, photons evolve the same way as neutrinos, they are temporarily, they remain blackbody and their temperature decreases with the scale factor. So, the ratio between photon temperatures and neutrino temperatures was in, sort of implanted at the time of electron annihilation. And the neutrinos are colder than the photons by the factor of 1.4, so there's less energy in neutrinos than there is in photons, but there is definitely an ambient cosmic neutrino radiation flying around. But that's not what we're about. We're talking about the neutrinos, about the neutrons and the protons because that's what it takes to make Helium. Notice that unlike in the present universe, in the present universe, you mostly find protons, neutrons only exist in nuclei. That's because they have billions of years to decay. Free neutrons do not exist. At these short times, neutrons have not decayed yet. Now, back when the universe was hot and dense the protons and neutrons are in chemical equilibrium, there are these rapid reactions that can convert neutrons to protons and protons to neutrons, in the presence of this sea of electrons and neutrinos, as the temperatures cool and the neutrinos decouple. And soon thereafter, most of the electrons and the positrons disappear. this reaction slow down by that time the neutron to proton ratio is decreased to about 0.22 because at this temperature, the mass difference is significant, it's either minus 1.5. Now, notice that once this ratio is achieved and temperatures have decreased, this ratio is frozen in essentially because reactions converting protons to neutrons and back, and vice-versa, no longer take place. So, from this moment on, these are the neutrons that you have. Now so now, you have a gas of neutrons and protons and, of course, over time, the neutrons decay so you have less and less neutrons. However, the universe is cooling and expanding and cooling, and when temperatures cool down to about a billion Kelvin, that is a time of about 180 seconds after the Big Bang, Deuterium is stable. So, if a proton and a neutron happen to be moving slowly enough next to each other and bind to form Deuterium, Deuterium will not be blown apart, photodisintegrated, by high energy photons once the energy of the photons is less than a billion kelvin. So until that time there was no Deuterium because if Deuterium, formed it would of been blown apart by a photon after 180 seconds after the Big Bang, Deuterium can form. Now, at this point essentially all of the neutrons that are left form Deuterium. How many neutrons are left? Well, they had a fraction of about 0.223 of neutrons to protons, but 180 seconds have gone by. The half-life of a neutron these are free neutrons, is about 600 seconds. you plug that into our half-life radioactive decay formula, remembering that neutrons decay to protons so it's parent to daughter ratio the number of neutrons has decreased, protons increased, The ratio has approximately halved, by this time, only about 12% of the baryons in the universe are neutrons. And now, once Deuterium is stable a neutron inside the Deuteron is stable, neutrons stop decaying. Essentially, all of the remaining neutrons are bound up in Deuterium and very rapidly thereafter, they formed a very stable alpha particle nucleus. So, essentially, all of the neutrons that survive produce Helium. And so, we get left with a Helium nuclei and three protons and no more neutrons. So, what does this predict about how many Helium nuclei you will have formed? Well, you can figure it out. how many of the nuclei that we have left are Helium nuclei? Well, each Helium nucleus requires 2 protons, 2, and 2 neutrons, since we had this many neutrons, this was our neutron to proton ratio, divide that by 2, that's sort of a count of how many neutrons how many Helium nuclei were created. How many particles what is the total number of particles? Well, we had a sort of the total number of neutrons plus protons. Add that up to 1 but then each new, each formation of a Helium nucleus took away 2 protons and took away 2 neutrons. So this many this many Helium nuclei took away four particles, replaced them by one so each Helium nucleus reduced the number by three. Plug in these numbers, you find that 7.5% of all the particles that are left in your all the baryons that are left are Helium nuclei and, of course, the others are protons. And any free neutrons that were left around that did not get stopped in, will rapidly within, you know, a few minutes, decay and so you'll, you'll end up with protons and alpha particles, that's all you'll end up with. So this is the fraction of the universe that you predict by this very rough calculation, will be Helium and in terms of mass, since the mass of a Helium nucleus is 4 times the mass of a proton, the mass fraction of Helium that you predict is about 30%. this is not bad. Remember, what we observe is about a quarter of the mass of the universe is in Helium. This very rough calculation produces an result that is very close to correct, a more refined calculation produces agreement. Notice that since essentially, all I needed to know was the ratio of neutrons to protons, it's very insensitive to details. the rate at which the universe cools, it's a radiation dominated universe, that has to do with the density of photons in the universe which I know because I measure the cosmic microwave background radiation. I know the energy density in the thermal microwave background. Today, I can extrapolate that by energy conservation back to those times. There is very little ambiguity. There's no free paramiters. And then, that get, that sets the time rate for all of these reactions to occur and basically nothing depends on any of the details the fraction of the universe, the protons and the neutrons that are converted to Helium atoms is a very robust prediction. Okay. So, we can understand where Helium came from. But about other nuclei, remember, gamma was trying to produce all nucleons, all nuclear, nuclear species. It turns out that fusion to heavier nuclei than Helium is very inefficient, but you form some small fraction of trace amounts of lithium and excitingly a little bit of Helium 3 and excitingly a fraction of, a small fraction of Deuterium. So, some of the deuterons did not fuse to form Helium and how many of them did not fuse to form Helium depends on the speed in which the universe expands driven by, remember, the density of the photon gas, relative to the density of nucleons because the denser nucleons are, the more rapid nuclear reactions are. So the abundance of Deuterium is very sensitive to this ratio of the density of baryons to the density of radiation and since today, density predicts the density then you can put constraints on the baryon density relative to the density of radiation, which remember, is known because this is basically sigma times 2.7k^4/2c. I know this. Well, this is rho radiation at current time. The background radiation gives me omegaR, precisely. So, this gives me great, strong constraints on the baryon density. This, in the sense, tells us two things. one is it tells us that not more than 5% of the total energy of the universe or the critical density could possibly be baryons, else we would have been left with lots more Deuterium. And I should point out that there are very few processes after the Big Bang that are likely to form Deuterium without producing alpha this is a a process of Nuclear Physics. and furthermore, it tells us that so, so that if we find that the density of dust of matter, non-relativistic matter in the universe, is larger than that 5%, then the remaining amount must be non-baryonic, and therefore, this is the 25% of the universe, that we think is composed of dark matter. This is one of the strongest constraints. you can, of course, do some more refined calculations that take into account both the concentration of Helium and of various isotopes and as I said, the trace amount of Lithium that was produced and so, this gives us a constraint on Cosmology. Moreover, if you tweak your model of particle Physics by all kinds of additions to the standard model trying to understand as we will see theories beyond the standard model, they might make small modifications to the rates of these nuclear reactions. things are extremely sensitive to the rates of nuclear reaction. For example, you can do a rather straight forward calculation that shows that if there were more than three, remember, there were three species of light neutrinos the muon neutrino, the electron neutrino, and the tau neutrino. more than three species of light neutrino would lead to unacceptable to Deuterium concentrations that are incompatible with the observation and so, in that sense, we know there cannot be a fourth as yet undetected neutrino species because it would ruin Big Bang nucleosynthesis, a very sensitive test of our understanding both of Cosmology and of particle Physics and one of the great successes of Big Bang Cosmology